You will need access to V$ views, V$SESSION, V$PROCESSS, V$SQLAREA. Also, V$OPEN_CURSOR will have all currently...
From V$SESSION you can get the SID and SERIAL#.
As a DBA, you can kill the session using the following command. Note: SID and SERIAL# values are separated by a comma and are within single quotes.
ALTER SYSTEM KILL SESSION 'SID, SERIAL#'
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